Publications HAL

2023

Journal articles

titre
Spontaneous Modulation Doping in Semi‐Crystalline Conjugated Polymers Leads to High Conductivity at Low Doping Concentration
auteur
Aditya Dash, Shubhradip Guchait, Dorothea Scheunemann, Vishnu Vijayakumar, Nicolas Leclerc, Martin Brinkmann, Martijn Kemerink
article
Advanced Materials, 2023, ⟨10.1002/adma.202311303⟩
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Abstract The possibility to control the charge carrier density through doping is one of the defining .....
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Journal articles
DOI
DOI : 10.1002/adma.202311303
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https://hal.science/hal-04389942/file/Dash%20et%20al%20-%20main%20-%20R1%20%28production%29%281%29.pdf BibTex
titre
Interplay between Side Chain Density and Polymer Alignment: Two Competing Strategies for Enhancing the Thermoelectric Performance of P3HT Analogues
auteur
Peter Gilhooly-Finn, Ian Jacobs, Olivier Bardagot, Yasser Zaffar, Antoine Lemaire, Shubhradip Guchait, Lu Zhang, Mark Freeley, William Neal, Fanny Richard, Matteo Palma, Natalie Banerji, Henning Sirringhaus, Martin Brinkmann, Christian Nielsen
article
Chemistry of Materials, 2023, ⟨10.1021/acs.chemmater.3c01680⟩
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Journal articles
DOI
DOI : 10.1021/acs.chemmater.3c01680
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https://hal.science/hal-04265399/file/Article-Finn-Accepted.pdf BibTex
titre
High-Temperature Rubbing: An Effective Method to Fabricate Large-Scale Aligned Semiconducting and Conducting Polymer Films for Applications in Organic Electronics
auteur
Shubhradip Guchait, Yuhan Zhong, Martin Brinkmann
article
Macromolecules, 2023, ⟨10.1021/acs.macromol.3c01073⟩
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Conjugated polymers (CPs) are ubiquitous in plastic electronics in the form of semi-conducting and c .....
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Journal articles
DOI
DOI : 10.1021/acs.macromol.3c01073
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titre
Impact of Regioregularity on Alignment and Thermoelectric Properties of Sequentially Doped and Oriented Films of Poly(3-hexylthiophene)
auteur
Shubhradip Guchait, Laurent Herrmann, Karim Kadri, Nicolas Leclerc, François Tran Van, Martin Brinkmann
article
ACS Applied Polymer Materials, 2023, 5 (7), pp.5676-5686. ⟨10.1021/acsapm.3c00972⟩
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Alignment of conjugated polymers such as regioregular poly(3-hexylthiophene-2,5-diyl) (rr-P3HT) is a .....
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Journal articles
DOI
DOI : 10.1021/acsapm.3c00972
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titre
Evolution of Length-Dependent Properties of Discrete n-Type Oligomers Prepared via Scalable Direct Arylation
auteur
Rukiya Matsidik, Hartmut Komber, Martin Brinkmann, Karl Sebastian Schellhammer, Frank Ortmann, Michael Sommer
article
Journal of the American Chemical Society, 2023, 145 (15), pp.8430. ⟨10.1021/jacs.3c00058⟩
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Efficient organic electronic devices are fabricated from both small molecules and disperse polymers, .....
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DOI
DOI : 10.1021/jacs.3c00058
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titre
Controlling orientation, polymorphism, and crystallinity in thin films of poly(lactic‐acid) homopolymer and stereocomplex aligned by high temperature rubbing
auteur
Marion Brosset, Laurent Herrmann, Céline Kiefer, Thierry Falher, Martin Brinkmann
article
Journal of Applied Polymer Science, 2023, 140 (8), pp.e53532. ⟨10.1002/app.53532⟩
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High temperature rubbing is a fast and low-cost method that can align semi-crystalline polymers such .....
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Journal articles
DOI
DOI : 10.1002/app.53532
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https://cea.hal.science/cea-03956719/file/Article-Marion-090822-j%20ApplPolySci-revised.pdf BibTex
titre
Preparation of oriented poly(lactic acid) thin films by a combination of high temperature rubbing and thermal annealing: Impact of annealing parameters on structure, polymorphism and morphology
auteur
Marion Brosset, Laurent Herrmann, Thierry Falher, Martin Brinkmann
article
Journal of Polymer Science, 2023, ⟨10.1002/pol.20220740⟩
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High temperature rubbing is a fast and low-cost method to prepare highly oriented films of polymers. .....
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Journal articles
DOI
DOI : 10.1002/pol.20220740
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https://cea.hal.science/cea-03956730/file/Journal%20of%20Polymer%20Science%20-%202023%20-%20Brosset%20-%20Preparation%20of%20oriented%20poly%20lactic%20acid%20thin%20films%20by%20a%20combination%20of%20high.pdf BibTex
titre
Self-Powered Dynamic Glazing Based on Nematic Liquid Crystals and Organic Photovoltaic Layers for Smart Window Applications
auteur
Sadiara Fall, Jing Wang, Thomas Regrettier, Nicolas Brouckaert, Olzhas Ibraikulov, Nicolas Leclerc, Yaochen Lin, Mohammed Ibn Elhaj, Lachezar Komitov, Patrick Lévêque, Yuhan Zhong, Martin Brinkmann, Malgosia Kaczmarek, Thomas Heiser
article
ACS Applied Materials & Interfaces, 2023, 15 (3), ⟨10.1021/acsami.2c21727⟩
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DOI
DOI : 10.1021/acsami.2c21727
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Conference papers

titre
Side chains in organic conjugated materials, a key parameter
auteur
Nicolas Leclerc, Olzhas A Ibraikulov, Pablo Durand, Huiyan Zeng, Benoît Heinrich, Thomas Heiser, Patrick Lévêque, Martin Brinkmann, Stéphane Méry
article
SCF 2023 (Société Chimique de France), Jun 2023, Nantes, France
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2022

Journal articles

titre
Optimizing chain alignment and preserving the pristine structure of single-ether based PBTTT helps improve thermoelectric properties in sequentially doped thin films
auteur
Martin Brinkmann, Pablo Durand, Shubhradip Guchait, Laurent Herrmann, Celine Kiefer, Nicolas Leclerc, Huiyan Zeng
article
Journal of Materials Chemistry C, 2022, ⟨10.1039/D2TC03600B⟩
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Doped polymer semi-conductors are of central interest in material science for their interesting char .....
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Journal articles
DOI
DOI : 10.1039/D2TC03600B
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https://hal.science/hal-03795371/file/ArticleHuiyan-Pablo-accepted.pdf BibTex
titre
Single ether-based side chains in conjugated polymers: Towards power factors of 2.9 mW/m . K 2
auteur
Pablo Durand, Huiyan Zeng, Till Biskup, Vishnu Vijayakumar, Viktoriia Untilova, Céline Kiefer, Benoît Heinrich, Laurent Herrmann, Martin Brinkmann, Nicolas Leclerc
article
Advanced Energy Materials, 2022, 12 (2), pp.2103049. ⟨10.1002/aenm.202103049⟩
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Combining side chain engineering and controlled alignment of PBTTT is an effective strategy to produ .....
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Journal articles
DOI
DOI : 10.1002/aenm.202103049
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https://hal.science/hal-03795437/file/article%20_Leclerc_Production%20data.pdf BibTex
titre
Preferential Location of Dopants in the Amorphous Phase of Oriented Regioregular Poly(3‐hexylthiophene‐2,5‐diyl) Films Helps Reach Charge Conductivities of 3000 S cm −1
auteur
Yuhan Zhong, Viktoriia Untilova, Dominique Muller, Shubhradip Guchait, Céline Kiefer, Laurent Herrmann, Nicolas Zimmermann, Marion Brosset, Thomas Heiser, Martin Brinkmann
article
Advanced Functional Materials, 2022, 32 (30), pp.2202075. ⟨10.1002/adfm.202202075⟩
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Doping polymer semiconductors is a central topic in plastic electronics and especially in the design .....
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Journal articles
DOI
DOI : 10.1002/adfm.202202075
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https://hal.science/hal-03760656/file/Manuscriptfinal.pdf BibTex

2021

Journal articles

titre
Growth, morphology and molecular orientation of controlled Indigo thin films on silica surfaces
auteur
Arianna Rivalta, Cristiano Albonetti, Davide Biancone, Michele Della Ciana, Simone d'Agostino, Laure Biniek, Martin Brinkmann, Andrea Giunchi, Tommaso Salzillo, Aldo Brillante, Raffaele Guido Della Valle, Elisabetta Venuti
article
Surfaces and Interfaces, 2021, 24, pp.101058. ⟨10.1016/j.surfin.2021.101058⟩
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Thin films of the natural semiconductor indigo have been grown on Si/SiO2 substrates by physical vap .....
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Journal articles
DOI
DOI : 10.1016/j.surfin.2021.101058
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https://hal.science/hal-03359189/file/INDIGO-S%26I-FINAL%20REVISED.pdf BibTex
titre
Organic and hybrid thermoelectrics
auteur
Martijn Kemerink, Christian Müller, Michael Chabinyc, Martin Brinkmann
article
Applied Physics Letters, 2021, 119 (26), pp.260401. ⟨10.1063/5.0082126⟩
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Journal articles
DOI
DOI : 10.1063/5.0082126
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https://hal.science/hal-03632212/file/Editorial-APL-Martin%20final.pdf BibTex
titre
Electrical and mechanical properties of intrinsically flexible and stretchable PEDOT polymers for thermotherapy
auteur
Amélie Schultheiss, Amélie Revaux, Alexandre Carella, Martin Brinkmann, Huiyan Zeng, Renaud Demadrille, Jean-Pierre Simonato
article
ACS Applied Polymer Materials, 2021, 3 (11), pp.5942-5949. ⟨10.1021/acsapm.1c01203⟩
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For wearable applications such as electronic skin and biosensors, stretchable conductors are require .....
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Journal articles
DOI
DOI : 10.1021/acsapm.1c01203
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https://hal.science/hal-03636178/file/Article%20by%20Shultheiss%20et%20al%20%28final%29.pdf BibTex
titre
High thermal conductivity states and enhanced figure of merit in aligned polymer thermoelectric materials
auteur
Thibault Degousée, Viktoriia Untilova, Vishnu Vijayakumar, Xinzhao Xu, Yiwei Sun, Matteo Palma, Martin Brinkmann, Laure Biniek, Oliver Fenwick
article
Journal of Materials Chemistry A, 2021, 9 (29), pp.16065-16075. ⟨10.1039/D1TA03377H⟩
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Control of morphology in polymer thermoelectric materials is critical to their performance. In this .....
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Journal articles
DOI
DOI : 10.1039/D1TA03377H
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https://hal.science/hal-03357760/file/JChemMaterA-%20In-plane%20thermal%20conductivity%20of%20aligned%20P3HT%20for%20thermoelectric_POST_REVIEW_TD_20210626%281%29-1.pdf BibTex
titre
Fabrication of Oriented n‐Type Thermoelectric Polymers by Polarity Switching in a DPP‐Based Donor–Acceptor Copolymer Doped with FeCl 3
auteur
Huiyan Zeng, Mohammed Mohammed, Viktoriia Untilova, Olivier Boyron, Nicolas Berton, Patrice Limelette, Bruno Schmaltz, Martin Brinkmann
article
Advanced Electronic Materials, 2021, 7 (5), pp.2000880. ⟨10.1002/aelm.202000880⟩
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n‐Type‐doped polymers are key elements to fabricate all‐polymer thermoelectric generators but .....
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Journal articles
DOI
DOI : 10.1002/aelm.202000880
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https://univ-tours.hal.science/hal-03192473/file/Paper-Huiyan-PolaritySwitching-Revised.pdf BibTex

2020

Journal articles

titre
Influence of dopant size and doping method on the structure and thermoelectric properties of PBTTT films doped with F 6 TCNNQ and F 4 TCNQ
auteur
Vishnu Vijayakumar, Pablo Durand, Huiyan Zeng, Viktoriia Untilova, Laurent Herrmann, Patrick Algayer, Nicolas Leclerc, Martin Brinkmann
article
Journal of Materials Chemistry C, 2020, ⟨10.1039/d0tc02828b⟩
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Journal articles
DOI
DOI : 10.1039/d0tc02828b
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https://hal.science/hal-02986741/file/paper-F6TCNNQ-2020-revised.pdf BibTex
titre
Rubbing and Drawing: Generic Ways to Improve the Thermoelectric Power Factor of Organic Semiconductors?
auteur
Dorothea Scheunemann, Vishnu Vijayakumar, Huiyan Zeng, Pablo Durand, Nicolas Leclerc, Martin Brinkmann, Martijn Kemerink
article
Advanced Electronic Materials, 2020, 6 (8), pp.2000218. ⟨10.1002/aelm.202000218⟩
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Highly oriented polymer films can show considerable anisotropy in the thermoelec-tric properties lea .....
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DOI
DOI : 10.1002/aelm.202000218
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https://hal.science/hal-03009825/file/Scheunemann-AdvElectMater.pdf BibTex
titre
Insights into the structural complexity of semi-crystalline polymer semiconductors: electron diffraction contributions
auteur
Martin Brinkmann
article
Materials Chemistry Frontiers, 2020, 4 (7), pp.1916-1929. ⟨10.1039/d0qm00230e⟩
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Journal articles
DOI
DOI : 10.1039/d0qm00230e
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https://hal.science/hal-02888857/file/MaterChemFrontieresSubmitted-revised.pdf BibTex
titre
Crystallization and OFET Performance of a Hydrogen‐Bonded Quaterthiophene
auteur
Jan Gebers, Bilal Özen, Lucia Hartmann, Michel Schaer, Stéphane Suarez, Philippe Bugnon, Rosario Scopelliti, Hans-Georg Steinrück, Oleg Konovalov, Andreas Magerl, Martin Brinkmann, Riccardo Petraglia, Piotr De Silva, Clémence Corminboeuf, Holger Frauenrath
article
Chemistry - A European Journal, 2020, ⟨10.1002/chem.201904562⟩
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Crystalline thin films of π-conjugated molecules are relevant as the active layers in organic elect .....
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DOI
DOI : 10.1002/chem.201904562
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https://hal.science/hal-02888863/file/OFET%20Quaterthiophene%20Acetamide%20R1%20Manuscript.pdf BibTex
titre
Control of Chain Alignment and Crystallization Helps Enhance Charge Conductivities and Thermoelectric Power Factors in Sequentially Doped P3HT:F 4 TCNQ Films
auteur
Viktoriia Untilova, Till Biskup, Laure Biniek, Vishnu Vijayakumar, Martin Brinkmann
article
Macromolecules, 2020, ⟨10.1021/acs.macromol.9b02389⟩
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Journal articles
DOI
DOI : 10.1021/acs.macromol.9b02389
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https://hal.science/hal-02521023/file/Paper-Vik-MBoct2019-Lotz-Till-Vi-lb-revised%20copie.pdf BibTex
titre
High Thermoelectric Power Factor of Poly(3-hexylthiophene) through In-Plane Alignment and Doping with a Molybdenum Dithiolene Complex
auteur
Viktoriia Untilova, Jonna Hynynen, Anna I Hofmann, Dorothea Scheunemann, Yadong Zhang, Stephen Barlow, Martijn Kemerink, Seth R Marder, Laure Biniek, Christian Müller, Martin Brinkmann
article
Macromolecules, In press, ⟨10.1021/acs.macromol.0c01223⟩
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DOI
DOI : 10.1021/acs.macromol.0c01223
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https://hal.science/hal-02913826/file/Untilova%20et%20al.%20-%20manuscript_revised.pdf BibTex
titre
Competing Molecular Packing of Blocks in a Lamella-Forming Carbohydrate- block -poly(3-hexylthiophene) Copolymer
auteur
Yoko Sakai-Otsuka, Yoshiharu Nishiyama, Jean-Luc Putaux, Martin Brinkmann, Toshifumi Satoh, Wen-Chang Chen, Redouane Borsali
article
Macromolecules, 2020, 53 (20), pp.9054-9064. ⟨10.1021/acs.macromol.0c01801⟩
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A molecular packing model of poly(3-hexylthiophene)-block-peracetylated maltopheptaose (P3HT-b-AcMal .....
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Journal articles
DOI
DOI : 10.1021/acs.macromol.0c01801
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https://cnrs.hal.science/hal-03075544/file/Yoko%20Macromolecules%202020.pdf BibTex

2019

Journal articles

titre
Impact of Competing Crystallization Processes on the Structure of All-Conjugated Donor–Acceptor Block Copolymers P3HT- b -PNDIT2 in Highly Oriented Thin Films
auteur
Viktoriia Untilova, Fritz Nübling, Laure Biniek, Michael Sommer, Martin Brinkmann
article
ACS Applied Polymer Materials, 2019, 1 (7), pp.1660-1671. ⟨10.1021/acsapm.9b00220⟩
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Journal articles
DOI
DOI : 10.1021/acsapm.9b00220
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https://hal.science/hal-02338694/file/Article-P3HT-b-PNDIT2_revisedMB-nothighlighted.pdf BibTex
titre
Effect of Alkyl Side Chain Length on Doping Kinetics, Thermopower, and Charge Transport Properties in Highly Oriented F 4 TCNQ-Doped PBTTT Films
auteur
Vishnu Vijayakumar, Elena Zaborova, Laure Biniek, Huiyan Zeng, Laure Herrmann, Alain Carvalho, Olivier Boyron, Nicolas Leclerc, Martin Brinkmann
article
ACS Applied Materials & Interfaces, 2019, 11 (5), pp.4942-4953. ⟨10.1021/acsami.8b17594⟩
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Doping of polymer semiconductors such as poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) ( .....
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DOI
DOI : 10.1021/acsami.8b17594
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https://hal.science/hal-02194242/file/Paper-Vishnu1-finalsubmitted%20Alkyl%20%281%29.pdf BibTex
titre
Block Junction-Functionalized All-Conjugated Donor–Acceptor Block Copolymers
auteur
Fritz Nübling, Thomas Hopper, Brooke Kuei, Hartmut Komber, Viktoriia Untilova, Simon Schmidt, Martin Brinkmann, Enrique Gomez, Artem Bakulin, Michael Sommer
article
ACS Applied Materials & Interfaces, 2019, 11 (1), pp.1143-1155. ⟨10.1021/acsami.8b18608⟩
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Junction-functionalized donor–acceptor (D–A) block copolymers (BCPs) enable spatial and electron .....
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Journal articles
DOI
DOI : 10.1021/acsami.8b18608
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https://hal.science/hal-02045729/file/180920_Nu%CC%88bling%20block%20junction%20functionalized%20DA%20BCP_ACSApplInterfaces.pdf BibTex
titre
From Isotropic to Anisotropic Conductivities in P(NDI2OD-T2) by (Electro-)Chemical Doping Strategies
auteur
Yannic Gross, Daniel Trefz, Daniel Bauer, Carsten Dingler, Vishnu Vijayakumar, Viktoriia Untilova, Laure Biniek, Martin Brinkmann, Sabine Ludwigs
article
Chemistry of Materials, 2019, 31 (9), pp.3542-3555. ⟨10.1021/acs.chemmater.9b00977⟩
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Both electrochemical and chemical doping of the n-type regioregular polymer poly{[N,N′-bis(2-octyl .....
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DOI
DOI : 10.1021/acs.chemmater.9b00977
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https://hal.science/hal-02194239/file/Fromisoto.pdf BibTex
titre
Bringing Conducting Polymers to High Order: Toward Conductivities beyond 10 5 S cm −1 and Thermoelectric Power Factors of 2 mW m −1 K −2
auteur
Yuhan Zhong, Vishnu Vijayakumar, Viktoriia Untilova, Mounib Bahri, Laurent Herrmann, Laure Biniek, Nicolas Leclerc, Martin Brinkmann
article
Advanced Energy Materials, 2019, 9 (24), pp.1900266. ⟨10.1002/aenm.201900266⟩
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Here, an effective design strategy of polymer thermoelectric materials based on structural control i .....
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DOI
DOI : 10.1002/aenm.201900266
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https://hal.science/hal-02194240/file/ArticleBigConductivity_Final-Revised.pdf BibTex
titre
Original polymorphism in a naphthalene bisimide π-conjugated organogelator: a complex interplay between hydrogen bonding and heterocycle π-stacking
auteur
Morgane Diebold, Elliot Christ, Laure Biniek, Lydia Karmazin, Benoît Heinrich, Christophe Contal, Suhrit Ghosh, Philippe Mesini, Martin Brinkmann
article
Journal of Materials Chemistry C, 2019, ⟨10.1039/C9TC04402G⟩
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This study focuses on the structure of different supramolecular assemblies formed in the gel phase a .....
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DOI
DOI : 10.1039/C9TC04402G
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https://hal.science/hal-02338686/file/Article-Morgane-Polymorphisme%20Soumis.pdf BibTex
titre
Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors
auteur
Alessandro Luzio, Fritz Nübling, Jaime Martin, Daniele Fazzi, Philipp Selter, Eliot Gann, Christopher Mcneill, Martin Brinkmann, Michael Ryan Hansen, Natalie Stingelin, Michael Sommer, Mario Caironi
article
Nature Communications, 2019, 10, pp.3365. ⟨10.1038/s41467-019-11125-9⟩
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Recent demonstrations of inverted thermal activation of charge mobility in polymer field-effect tran .....
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DOI
DOI : 10.1038/s41467-019-11125-9
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https://hal.science/hal-02338673/file/submitted.pdf BibTex

2018

Journal articles

titre
Tuning Orientational Order of Highly Aggregating P(NDI2OD-T 2 ) by Solvent Vapor Annealing and Blade Coating
auteur
Daniel Trefz, Yannic Gross, Carsten Dingler, Roman Tkachov, Amer Hamidi-Sakr, Anton Kiriy, Christopher Mcneill, Martin Brinkmann, Sabine Ludwigs
article
Macromolecules, 2018, 52 (1), pp.43-54
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titre
Structure and charge transport anisotropy of polythieno[3,4- b ]-thiophene- co -benzodithiophene (PTB7) oriented by high-temperature rubbing
auteur
Laure Biniek, Amer Hamidi-Sakr, Linda Grodd, Stéphanie Escoubas, Yannick Dappe, Souren Grigorian, Marc Schmutz, Martin Brinkmann
article
Advanced Electronic Materials, 2018, 4 (10), pp.1700480. ⟨10.1002/aelm.201700480⟩
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Structure determination in high performance polymer semiconductors such as polythieno[3,4‐b]‐thi .....
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DOI
DOI : 10.1002/aelm.201700480
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https://hal.science/hal-02023024/file/Article-Structure-PTB7-sept2017AdvElectMatRevisedfinal2lb.pdf BibTex
titre
In Situ Synthesis of Ternary Block Copolymer/Homopolymer Blends for Organic Photovoltaics
auteur
Fritz Nübling, Dan Yang, Peter Müller-Buschbaum, Martin Brinkmann, Michael Sommer
article
ACS Applied Materials & Interfaces, 2018, 10 (21), pp.18149-18160
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https://hal.science/hal-02045727/file/Ternary%20blends%20P3HT%20PNDIT2_final.pdf BibTex
titre
Poly(3-hexylthiophene) revisited – Influence of film deposition on the electrochemical behaviour and energy levels
auteur
Kirsten Bruchlos, Daniel Trefz, Amer Hamidi-Sakr, Martin Brinkmann, Jürgen Heinze, Adrian Ruff, Sabine Ludwigs
article
Electrochimica Acta, 2018, 269, pp.299-311. ⟨10.1016/j.electacta.2018.02.126⟩
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DOI
DOI : 10.1016/j.electacta.2018.02.126
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titre
Segregated versus Disordered Stacking in Two Low Bandgap Alternated Copolymers for Photovoltaic Applications: Impact of Polymorphism on Optical Properties
auteur
Yuhan Zhong, Laure Biniek, Nicolas Leclerc, Stéphanie Ferry, Martin Brinkmann
article
Macromolecules, 2018, 51 (11), pp.4238-4249. ⟨10.1021/acs.macromol.8b00378⟩
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Structure–property correlations are often hampered by insufficient structural insight into the cry .....
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DOI
DOI : 10.1021/acs.macromol.8b00378
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https://hal.science/hal-02338356/file/ArticleYuhanSF038-PCE11%C2%A0.pdf BibTex

2017

Journal articles

titre
Supramolecular organization of a H-bonded perylene bisimide organogelator determined by transmission electron microscopy, grazing incidence X-ray diffraction and polarized infra-red spectroscopy
auteur
Alexandru Sarbu, Patrick Hermet, David Maurin, David Djurado, Laure Biniek, Morgane Diebold, Jean-Louis Bantignies, Philippe Mesini, Martin Brinkmann
article
Physical Chemistry Chemical Physics, 2017, 19 (48), pp.32514-32525. ⟨10.1039/c7cp06761e⟩
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An organogelator based on a N,N′-substituted H-bonding perylenebisimide (PBI-C10) self-assembles t .....
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DOI
DOI : 10.1039/c7cp06761e
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titre
Tuning Aggregation by Regioregularity for High-Performance n-Type P(NDI2OD-T 2 ) Donor–Acceptor Copolymers
auteur
Yannic Gross, Daniel Trefz, Roman Tkachov, Viktoriia Untilova, Martin Brinkmann, Gisela Schulz, Sabine Ludwigs
article
Macromolecules, 2017, 50 (14), pp.5353-5366
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titre
A Versatile Method to Fabricate Highly In-Plane Aligned Conducting Polymer Films with Anisotropic Charge Transport and Thermoelectric Properties: The Key Role of Alkyl Side Chain Layers on the Doping Mechanism
auteur
Amer Hamidi-Sakr, Laure Biniek, Jean-Louis Bantignies, David Maurin, Laure Herrmann, Nicolas Leclerc, Patrick Lévêque, Vishnu Vijayakumar, Nicolas Zimmermann, Martin Brinkmann
article
Advanced Functional Materials, 2017, 27 (25), pp.1700173. ⟨10.1002/adfm.201700173⟩
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A general method is proposed to produce oriented and highly crystalline conducting polymer layers. I .....
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DOI : 10.1002/adfm.201700173
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titre
Insulated molecular wires: sheathing semiconducting polymers with organic nanotubes through heterogeneous nucleation
auteur
Gijo Raj, Athmane Boulaoued, Johann Lacava, Laure Biniek, Philippe J. Mesini, Martin Brinkmann, Jérôme Faure-Vincent, Jean-Michel Guenet
article
Advanced Electronic Materials, 2017, 3 (1), pp.1600370. ⟨10.1002/aelm.201600370⟩
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Insulated molecular wires formed from organic molecules may have promising applications in organic a .....
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DOI : 10.1002/aelm.201600370
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titre
The Role of Local Instabilities in Fluid Invasion into Permeable Media
auteur
Kamaljit Singh, Hagen Scholl, Martin Brinkmann, Marco Di Michiel, Mario Scheel, Stephan Herminghaus, Ralf Seemann
article
Scientific Reports, 2017, 7, 11 p. ⟨10.1038/s41598-017-00191-y⟩
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Wettability is an important factor which controls the displacement of immiscible fluids in permeable .....
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DOI : 10.1038/s41598-017-00191-y
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titre
Charge separation in an acceptor–donor–acceptor triad material with a lamellar structure
auteur
D. Rolland, J. C. Brauer, L. Hartmann, Laure Biniek, Martin Brinkmann, N. Banerji, H. Frauenrath
article
Journal of Materials Chemistry C, 2017, 5 (6), pp.1383-1393. ⟨10.1039/C6TC03786K⟩
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Linking covalently both electron donor and acceptor components is an efficient way to gain thermodyn .....
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DOI : 10.1039/C6TC03786K
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Conference papers

titre
Highly oriented and crystalline semi-conducting and conducting polymer films by high-temperature rubbing
auteur
Martin Brinkmann, Amer Hamidi Sakr, Laure Biniek, Patrick Lévêque, Jean-Louis Bantignies, David Maurin, Nicolas Leclerc
article
E-MRS spring-meeting, Strasbourg, France, mai 2017, May 2017, Strasbourg, France
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2016

Journal articles

titre
High-resolution noncontact AFM and Kelvin probe force microscopy investigations of self-assembled photovoltaic donor–acceptor dyads
auteur
Benjamin Grévin, Pierre-Olivier Schwartz, Laure Biniek, Martin Brinkmann, Nicolas Leclerc, Elena Zaborova, Stéphane Méry
article
Beilstein Journal of Nanotechnology, 2016, 7, pp.799-808. ⟨10.3762/bjnano.7.71⟩
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DOI : 10.3762/bjnano.7.71
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titre
Highly Oriented and Crystalline Films of a Phenyl-Substituted Polythiophene Prepared by Epitaxy: Structural Model and Influence of Molecular Weight
auteur
Amer Hamidi-Sakr, Daniel Schiefer, Sangeetha Covindarassou, Laure Biniek, Michael Sommer, Martin Brinkmann
article
Macromolecules, 2016, 49 (9), pp.3452-3462
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titre
Metal nanoparticle mediated space charge and its optical control in an organic hole-only device
auteur
Giovanni Ligorio, M.V. Nardi, R. Steyrleuthner, Dris Ihiawakrim, N. Crespo-Monteiro, Martin Brinkmann, D. Neher, Norbert Koch
article
Applied Physics Letters, 2016, 108 (15), ⟨10.1063/1.4945710⟩
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We reveal the role of localized space charges in hole-only devices based on an organic semiconductor .....
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DOI : 10.1063/1.4945710
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titre
Precise Control of Lamellar Thickness in Highly Oriented Regioregular Poly(3-Hexylthiophene) Thin Films Prepared by High-Temperature Rubbing: Correlations with Optical Properties and Charge Transport
auteur
Amer Hamidi-Sakr, Laure Biniek, Sadiara Fall, Martin Brinkmann
article
Advanced Functional Materials, 2016, 26 (3), pp.408-420. ⟨10.1002/adfm.201504096⟩
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Precise control of orientation and crystallinity is achieved in regioregular poly(3-hexylthiophene) .....
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DOI
DOI : 10.1002/adfm.201504096
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Conference papers

titre
Tackling down the low wind effect on SPHERE instrument
auteur
Jean-François Sauvage, Thierry Fusco, Masen Lamb, Julien Girard, Martin Brinkmann, Andrés Guesalaga, Peter Wizinowich, Jared O'Neal, Mamadou N'Diaye, Arthur Vigan, David Mouillet, Jean-Luc Beuzit, Markus Kasper, Miska Le Louarn, Julien Milli, Kjetil Dohlen, Benoit Neichel, Pierre Bourget, Pierre Haguenauer, Dimitri Mawet, Enrico Marchetti, Laird Close, Jean-Pierre Véran
article
SPIE Astronomical Telescopes + Instrumentation, Jul 2016, Edinburgh, United Kingdom. pp.990916, ⟨10.1117/12.2232459⟩
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SPHERE is the VLT second generation planet hunter instrument. Installed since May 2014 on UT3, the s .....
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DOI : 10.1117/12.2232459
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2015

Journal articles

titre
Structural Models of Poly(cyclopentadithiophene- alt -benzothiadiazole) with Branched Side Chains: Impact of a Single Fluorine Atom on the Crystal Structure and Polymorphism of a Conjugated Polymer
auteur
Florian Fischer, Navaphun Kayunkid, Daniel Trefz, Sabine Ludwigs, Martin Brinkmann
article
Macromolecules, 2015, 48 (12), pp.3974-3982
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titre
3D imaging of filaments in organic resistive memory devices
auteur
Yan Busby, N. Crespo-Monteiro, Maria Girleanu, Martin Brinkmann, Ovidiu Ersen
article
Organic Electronics, 2015, 16, pp.Pages 40-45. ⟨10.1016/j.orgel.2014.10.039⟩
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Filaments in organic and hybrid resistive memories are studied by combining advanced characterizatio .....
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DOI : 10.1016/j.orgel.2014.10.039
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titre
Zipper-like molecular packing of donor–acceptor conjugated co-oligomers based on perylenediimide
auteur
Laure Biniek, Pierre-Olivier Schwartz, Elena Zaborova, Benoît Heinrich, Nicolas Leclerc, Stéphane Mery, Martin Brinkmann
article
Journal of Materials Chemistry C, 2015, 3 (14), pp.3342-3349. ⟨10.1039/c5tc00221d⟩
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The molecular packing of a new class of perylene diimide-based acceptor-donor (A-D) co-oligomers has .....
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DOI : 10.1039/c5tc00221d
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titre
Reversible J- to H-aggregate transformation in thin films of a perylenebisimide organogelator
auteur
Alexandru Sarbu, Laure Biniek, Jean-Michel Guenet, Philippe Mesini, Martin Brinkmann
article
Journal of Materials Chemistry C, 2015, 3 (6), pp.1235-1242. ⟨10.1039/c4tc02444c⟩
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A perylene bisimide organogelator is shown to behave as a reversible stimuli responsive material: th .....
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DOI : 10.1039/c4tc02444c
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2014

Journal articles

titre
High-Temperature Rubbing: A Versatile Method to Align π-Conjugated Polymers without Alignment Substrate
auteur
Laure Biniek, Stéphanie Pouget, David Djurado, Eric Gonthier, Kim Tremel, Navaphun Kayunkid, Elena Zaborova, Nicolas Crespo-Monteiro, Olivier Boyron, Nicolas Leclerc, Sabine Ludwigs, Martin Brinkmann
article
Macromolecules, 2014, 47 (12), pp.3871-3879. ⟨10.1021/ma500762x⟩
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Mechanical rubbing of polymer films has been widely used in the liquid crystal display industry to p .....
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DOI : 10.1021/ma500762x
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titre
Perylenediimide-Based Donor–Acceptor Dyads and Triads: Impact of Molecular Architecture on Self-Assembling Properties
auteur
Pierre-Olivier Schwartz, Laure Biniek, Elena Zaborova, Benoît Heinrich, Martin Brinkmann, Nicolas Leclerc, Stéphane Mery
article
Journal of the American Chemical Society, 2014, 136 (16), pp.5981-5992
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titre
Intertwined Lamello-Columnar Coassemblies in Liquid-Crystalline Side-Chain Π-Conjugated Polymers: Toward a New Class of Nanostructured Supramolecular Organic Semiconductors
auteur
Danli Zeng, Ibtissam Tahar-Djebbar, Yiming Xiao, Farid Kameche, Navaphun Kayunkid, Martin Brinkmann, Daniel Guillon, Benoît Heinrich, Bertrand Donnio, Dimitri A. Ivanov, Emmanuelle Lacaze, David Kreher, Fabrice Mathevet, André-Jean Attias
article
Macromolecules, 2014, 47 (5), pp.1715-1731. ⟨10.1021/ma4020356⟩
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DOI : 10.1021/ma4020356
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titre
Orienting Semi-Conducting π-Conjugated Polymers
auteur
Martin Brinkmann, Lucia Hartmann, Laure Biniek, Kim Tremel, Navaphun Kayunkid
article
Macromolecular Rapid Communications, 2014, 35 (1), pp.9-26
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titre
Wetting Heterogeneities in Porous Media Control Flow Dissipation
auteur
Julie Murison, Benoît Semin, Jean-Christophe Baret, Stephan Herminghaus, Matthias Schröter, Martin Brinkmann
article
Physical Review Applied, 2014, 2 (3), pp.034002. ⟨10.1103/PhysRevApplied.2.034002⟩
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Pressure-controlled displacement of an oil-water interface is studied in dense packings of functiona .....
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DOI : 10.1103/PhysRevApplied.2.034002
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titre
Charging and exciton-mediated decharging of metal nanoparticles in organic semiconductor matrices
auteur
Giovanni Ligorio, Marco Nardi Vittorio, Christos Christodoulou, Ileana Florea, N. Crespo-Monteiro, Ovidiu Ersen, Martin Brinkmann, Norbert Koch
article
Applied Physics Letters, 2014, 104 (16), pp.163302-1. ⟨10.1063/1.4873347⟩
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Gold nanoparticles (Au-NPs) were deposited on the surface of n- and p-type organic semiconductors to .....
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DOI : 10.1063/1.4873347
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2013

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titre
Large-Scale Simultaneous Orientation of CdSe Nanorods and Regioregular Poly(3-hexylthiophene) by Mechanical Rubbing
auteur
Lucia Hartmann, David Djurado, Ileana Florea, Jean-François Legrand, Angela Fiore, Peter Reiss, Stephen Doyle, Alexeï Vorobiev, Stéphanie Pouget, Frédéric Chandezon, Ovidiu Ersen, Martin Brinkmann
article
Macromolecules, 2013, 46 (15), pp.6177-6186. ⟨10.1021/ma400880x⟩
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DOI : 10.1021/ma400880x
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titre
Design principles for superamphiphobic surfaces
auteur
Hans-Jürgen Butt, Ciro Semprebon, Periklis Papadopoulos, Doris Vollmer, Martin Brinkmann, Matteo Ciccotti
article
Soft Matter, 2013, 9 (2), pp.418 - 428. ⟨10.1039/c2sm27016a⟩
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To predict the properties of superamphiphobic layers we analyzed the wetting of a square and a hexag .....
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DOI : 10.1039/c2sm27016a
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2012

Journal articles

titre
Impact of Thermal Annealing on the Semicrystalline Nanomorphology of Spin-Coated Thin Films of Regioregular Poly(3-alkylthiophene)s as Observed by High-Resolution Transmission Electron Microscopy and Grazing Incidence X-ray Diffraction
auteur
Shabi Thankaraj Salammal, Eduard Mikayelyan, Souren Grigorian, Ullrich Pietsch, Nils Koenen, Ullrich Scherf, Navaphun Kayunkid, Martin Brinkmann
article
Macromolecules, 2012, 45 (13), pp.5575-5585
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2011

Journal articles

titre
2D Versus 3D Crystalline Order in Thin Films of Regioregular Poly(3-hexylthiophene) Oriented by Mechanical Rubbing and Epitaxy
auteur
Lucia Hartmann, Kim Tremel, Sureeporn Uttiya, Edward Crossland, Sabine Ludwigs, Navaphun Kayunkid, Christelle Vergnat, Martin Brinkmann
article
Advanced Functional Materials, 2011, 21 (21), pp.4047-4057
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titre
Orienting Semiconducting Nanocrystals on Nanostructured Polycarbonate Substrates: Impact of Substrate Temperature on Polymorphism and In-Plane Orientation
auteur
Christelle Vergnat, Virginie Landais, Jean-François Legrand, Martin Brinkmann
article
Macromolecules, 2011, 44 (10), pp.3817-3827
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2010

Journal articles

titre
Highly Oriented and Nanotextured Films of Regioregular Poly(3-hexylthiophene) Grown by Epitaxy on the Nanostructured Surface of an Aromatic Substrate
auteur
Martin Brinkmann, Christophe Contal, Navaphun Kayunkid, Tatjana Djuric, Roland Resel
article
Macromolecules, 2010, 43 (18), pp.7604-7610. ⟨10.1021/ma101313m⟩
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A simple method for the nanotexturing and orientation of regioregular poly(3-hexylthiophene) (P3HT) .....
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DOI : 10.1021/ma101313m
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titre
Structural Model of Regioregular Poly(3-hexylthiophene) Obtained by Electron Diffraction Analysis
auteur
Navaphun Kayunkid, Sureeporn Uttiya, Martin Brinkmann
article
Macromolecules, 2010, 43 (11), pp.4961-4967
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2009

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titre
Structure and Morphology in Highly Oriented Films of Poly(9,9-bis( n -octyl)fluorene-2,7-diyl) and Poly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl) Grown on Friction Transferred Poly(tetrafluoroethylene)
auteur
Martin Brinkmann, Nipaphat Charoenthai, Rakchart Traiphol, Phimwipha Piyakulawat, Joerg Wlosnewski, Udom Asawapirom
article
Macromolecules, 2009, 42 (21), pp.8298-8306
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titre
Epitaxial Growth of Highly Oriented Fibers of Semiconducting Polymers with a Shish-Kebab-Like Superstructure
auteur
Martin Brinkmann, Frédéric Chandezon, Robert Pansu, Carine Julien-Rabant
article
Advanced Functional Materials, 2009, 19 (17), pp.2759-2766
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titre
Epitaxial Growth of Highly Oriented Fibers of Semiconducting Polymers with a Shish-Kebab-Like Superstructure
auteur
Martin Brinkmann, Frédéric Chandezon, Robert Bernard Pansu, Carine Julien
article
Advanced Functional Materials, 2009, 19 (17), pp.2759-2766. ⟨10.1002/adfm.200900966⟩
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Highly oriented fibers of regioregular poly(3-alkylthiophene)s (P3ATs) showing a ldquoshish-kebabrdq .....
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DOI : 10.1002/adfm.200900966
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titre
Crystallization of an Aromatic Biopolyester
auteur
Roland Hany, Martin Brinkmann, Davide Ferri, René Hartmann, Ernst Pletscher, Daniel Rentsch, Manfred Zinn
article
Macromolecules, 2009, 42 (16), pp.6322-6326
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titre
Molecular Weight Dependence of Chain Packing and Semicrystalline Structure in Oriented Films of Regioregular Poly(3-hexylthiophene) Revealed by High-Resolution Transmission Electron Microscopy
auteur
Martin Brinkmann, Patrice Rannou
article
Macromolecules, 2009, 42 (4), pp.1125-1130
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titre
Synthesis and self-assembly in bulk of six-arm star-block copolymers with a C60 core
auteur
Bruno Schmaltz, Claude Mathis, Martin Brinkmann
article
Polymer, 2009, 50 (4), pp.966 - 972. ⟨10.1016/j.polymer.2008.12.034⟩
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DOI : 10.1016/j.polymer.2008.12.034
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2008

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titre
Ordered Ferroelectric PVDF−TrFE Thin Films by High Throughput Epitaxy for Nonvolatile Polymer Memory
auteur
Youn Jung Park, Seok Ju Kang, Bernard Lotz, Martin Brinkmann, Annette Thierry, Kap Jin Kim, Cheolmin Park
article
Macromolecules, 2008, 41 (22), pp.8648-8654
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titre
Synthesis and self-assembly in bulk of linear and Mikto-arm star block copolymers based on polystyrene and poly(glutamic acid)
auteur
Jerome Babin, Daniel Taton, Martin Brinkmann, Sébastien Lecommandoux
article
International Journal of Biological Macromolecules, 2008, 41 (4), pp.1384-1392. ⟨10.1021/ma70⟩
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Both AB linear-type and AB(2) miktoarm star-type amphiphilic block copolymers based on polystyrene ( .....
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DOI : 10.1021/ma70
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titre
Synthesis and Self-Assembly in Bulk of Linear and Mikto-Arm Star Block Copolymers Based on Polystyrene and Poly(glutamic acid)
auteur
Jérôme Babin, Daniel Taton, Martin Brinkmann, Sébastien Lecommandoux
article
Macromolecules, 2008, 41 (4), pp.1384-1392. ⟨10.1021/ma702071y⟩
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DOI : 10.1021/ma702071y
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2007

Journal articles

titre
Switching Liquid Morphologies on Linear Grooves
auteur
Krishnacharya Khare, Stephan Herminghaus, Jean-Christophe Baret, Bruce Law, Martin Brinkmann, Ralf Seemann
article
Langmuir, 2007, 23 (26), pp.12997-13006. ⟨10.1021/la701899u⟩
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DOI : 10.1021/la701899u
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titre
Oriented and Nanostructured Polycarbonate Substrates for the Orientation of Conjugated Molecular Materials and Gold Nanoparticles
auteur
Martin Brinkmann, Sirapat Pratontep, Christian Chaumont, Jean-Claude Wittmann
article
Macromolecules, 2007, 40 (26), pp.9420-9426
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titre
Directional Epitaxial Crystallization and Tentative Crystal Structure of Poly(9,9‘-di- n -octyl-2,7-fluorene)
auteur
Martin Brinkmann
article
Macromolecules, 2007, 40 (21), pp.7532-7541. ⟨10.1021/ma071390d⟩
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DOI : 10.1021/ma071390d
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titre
Directional Epitaxial Crystallization and Tentative Crystal Structure of Poly(9,9‘-di- n -octyl-2,7-fluorene)
auteur
Martin Brinkmann
article
Macromolecules, 2007, 40 (21), pp.7532-7541
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2006

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titre
Nanostructure of self-assembled rod-coil block copolymer films for photovoltaic applications
auteur
Thomas Heiser, G. Adamopoulos, Martin Brinkmann, U. Giovanella, S. Ould-Saad, Cyril Brochon, K. van de Wetering, Georges Hadziioannou
article
Thin Solid Films, 2006, 511-512, pp.219-223. ⟨10.1016/j.tsf.2005.12.134⟩
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The nanostructures of a series of rod-coil block copolymers, designed for photovoltaic applications, .....
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DOI : 10.1016/j.tsf.2005.12.134
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titre
Controlled grafting of polymer chains onto C60 and thermal stability of the obtained materials
auteur
Claude Mathis, Bruno Schmaltz, Martin Brinkmann
article
Comptes Rendus. Chimie, 2006, 9 (7-8), pp.1075 - 1084. ⟨10.1016/j.crci.2005.11.015⟩
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DOI : 10.1016/j.crci.2005.11.015
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titre
Wettability Control of Droplet Deposition and Detachment
auteur
Jean-Christophe Baret, Martin Brinkmann
article
Physical Review Letters, 2006, 96 (14), ⟨10.1103/PhysRevLett.96.146106⟩
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The conditions for droplet deposition on plane substrates are studied using electrowetting to contin .....
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DOI : 10.1103/PhysRevLett.96.146106
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2005

Journal articles

titre
Impact of structure and morphology on charge transport in semiconducting oligomeric thin-film devices
auteur
C. Melzer, Martin Brinkmann, W. Krasnikov, Georges Hadziioannou
article
ChemPhysChem, 2005, 6 (11), pp.2376-2382. ⟨10.1002/cphc.200500142⟩
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We investigated various thin-film morphologies of vacuum-deposited highly luminescent 2,5-di-n-octyl .....
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DOI : 10.1002/cphc.200500142
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2004

Journal articles

titre
Structure and Spectroscopic Properties of the Crystalline Structures Containing Meridional and Facial Isomers of Tris(8-hydroxyquinoline) Gallium(III)
auteur
Martin Brinkmann, Benjamin Fite, Sirapat Pratontep, Christian Chaumont
article
Chemistry of Materials, 2004, 16 (23), pp.4627-4633
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titre
Nanoscale Organization of Fullerenes by Self-Assembly in a Diblock Copolymer Host Matrix
auteur
Bruno Schmaltz, Martin Brinkmann, Claude Mathis
article
Macromolecules, 2004, 37 (24), pp.9056 - 9063. ⟨10.1021/ma048421e⟩
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DOI : 10.1021/ma048421e
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titre
Nanoscale Organization of Fullerenes by Self-Assembly in a Diblock Copolymer Host Matrix
auteur
Bruno Schmaltz, Martin Brinkmann, Claude Mathis
article
Macromolecules, 2004, 37 (24), pp.9056-9063. ⟨10.1021/ma048421e⟩
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DOI : 10.1021/ma048421e
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2000

Journal articles

titre
Correlation between Molecular Packing and Optical Properties in Different Crystalline Polymorphs and Amorphous Thin Films of mer -Tris(8-hydroxyquinoline)aluminum(III)
auteur
Martin Brinkmann, Grégory Gadret, Michele Muccini, Carlo Taliani, Norberto Masciocchi, Angelo Sironi
article
Journal of the American Chemical Society, 2000, 122 (21), pp.5147-5157
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